Rectified ethyl alcohol GOST 5962. Rectified ethyl alcohol from food raw materialstechnical conditionspreface. Food grade ethyl alcohol

RECTIFIED ETHYL ALCOHOL FROM FOOD RAW MATERIALS

1 area of use

2 Normative references

3 Classification

4 Technical requirements

5 Safety requirements

6 Acceptance rules

7 Methods of analysis

8 Transportation and storage

1 area of use

2 Normative references

3 Classification

4 Technical requirements

5 Safety requirements

6 Acceptance rules

8 Transportation and storage

Specifications

Specifications

Preface

5 Safety requirements

6 Acceptance rules

7 Methods of analysis

8 Transportation and storage

4.4 Marking

Bibliography

GOST 5962-2013

Group H74

INTERSTATE STANDARD

RECTIFIED ETHYL ALCOHOL FROM FOOD RAW MATERIALS

Specifications

Rectified ethyl alcohol from edible raw material. Specifications

MKS 67.160.10

Date of introduction 2014-07-01

Preface

The goals, basic principles and basic procedure for carrying out work on interstate standardization are established by GOST 1.0-92 "Interstate standardization system. Basic provisions" and GOST 1.2-2009 "Interstate standardization system. Interstate standards, rules and recommendations for interstate standardization. Rules for development, adoption, application, renewal and cancellation"

Standard information

1 DEVELOPED by the State Scientific Institution "All-Russian Research Institute of Food Biotechnology" of the Russian Agricultural Academy (VNIIPBT Russian Agricultural Academy)

2 INTRODUCED by the Federal Agency for Technical Regulation and Metrology (Rosstandart)

3 ADOPTED by the Interstate Council for Standardization, Metrology and Certification (protocol dated June 7, 2013 N 43)

The following voted for adoption:


Short name of the country according to MK (ISO 3166) 004-97		Abbreviated name of the national standardization body
Azerbaijan		Azstandard
		Ministry of Economy of the Republic of Armenia
Kazakhstan		Gosstandart of the Republic of Kazakhstan
Kyrgyzstan		Kyrgyzstandard
		Moldova-Standard
		Rosstandart
Tajikistan		Tajikstandard
Uzbekistan		Uzstandard

(Amendment. IUS No. 3-2016).

4 By Order of the Federal Agency for Technical Regulation and Metrology dated June 28, 2013 N 345-st, the interstate standard GOST 5962-2013 was put into effect as a national standard of the Russian Federation on July 1, 2014.

5 INTRODUCED FOR THE FIRST TIME

An amendment has been made, published in IUS No. 3, 2016

Amendment made by database manufacturer

Information about changes to this standard is published in the annual information index "National Standards", and the text of changes and amendments is published in the monthly information index "National Standards". In case of revision (replacement) or cancellation of this standard, the corresponding notice will be published in the monthly information index "National Standards". Relevant information, notifications and texts are also posted in the public information system - on the official website of the Federal Agency for Technical Regulation and Metrology on the Internet

This standard applies to rectified ethyl alcohol from grains of various types, potatoes, sugar beets, raw sugar, molasses and other sugar- and starch-containing food raw materials (except for fruit) and obtained by rectification of alcohol mash or rectification of raw ethyl alcohol, as well as produced from the head fraction of ethyl alcohol obtained during the production of alcohol from food raw materials.

Product safety requirements are set out in 4.1.3 (in terms of the volume fraction of methyl alcohol), labeling requirements - in 4.4, and packaging requirements - in 4.3.

This standard uses normative references to the following interstate standards:

GOST 12.1.007-76 System of occupational safety standards. Harmful substances. Classification and general safety requirements

GOST 12.1.044-89 (ISO 4589-84) System of occupational safety standards. Fire and explosion hazard of substances and materials. Nomenclature of indicators and methods for their determination

GOST 5105-82 Steel cans for fuel and oils. Specifications

GOST 6247-79 Welded steel barrels with rolling hoops on the body. Specifications

GOST 13950-91 Welded and rolled steel barrels with corrugations on the body. Specifications

GOST 14192-96 Marking of cargo

GOST 15846-2002 Products sent to the Far North and equivalent areas. Packaging, labeling, transportation and storage

GOST 19433-88 Dangerous goods. Classification and labeling

GOST 26319-84 Dangerous goods. Package

GOST 30536-2013 Vodka and ethyl alcohol from food raw materials. Gas chromatographic express method for determining the content of toxic microimpurities

GOST 31685-2012 Rectified ethyl alcohol from food raw materials. Method for determining the mass concentration of dry residue

GOST 31810-2012 Rectified ethyl alcohol from food raw materials. Determination of the mass concentration of volatile nitrogenous bases by capillary electrophoresis

GOST 32013-2013* Ethyl alcohol. Method for determining the presence of furfural
________________
* GOST 32013-2012 is in force on the territory of the Russian Federation, hereinafter in the text. - Database manufacturer's note.

GOST 32036-2013 Ethyl alcohol from food raw materials. Acceptance rules and analysis methods

GOST 32070-2013 Vodka and ethyl alcohol from food raw materials. Gas chromatographic method for determining the content of volatile acids and furfural

Note - When using this standard, it is advisable to check the validity of the reference standards in the public information system - on the official website of the Federal Agency for Technical Regulation and Metrology on the Internet or using the annual information index "National Standards", which was published as of January 1 of the current year, and on issues of the monthly information index "National Standards" for the current year. If the reference standard is replaced (changed), then when using this standard you should be guided by the replacing (changed) standard. If the reference standard is canceled without replacement, then the provision in which a reference is made to it is applied in the part that does not affect this reference.

3.1 Depending on the degree of purification, rectified ethyl alcohol from food raw materials is divided into:

- first grade (not used for the production of alcoholic beverages);

- highest purification;

- "Basis";

- "Extra";

- "Lux";

- "Alpha".

4.1 Characteristics

4.1.1 Ethyl rectified alcohol from food raw materials must be produced in accordance with the requirements of this standard for technological regulations and technological instructions for alcohol of a specific name, in compliance with the requirements or regulations in force in the territory of the state that has adopted the standard.

4.1.2 In terms of organoleptic indicators, rectified ethyl alcohol from food raw materials must meet the requirements specified in Table 1.

Table 1


Indicator name	Characteristic
Appearance	Transparent liquid without foreign particles
	Colorless liquid
Taste and smell	Characteristic of rectified ethyl alcohol of a specific name, produced from the appropriate raw materials, without the taste and odor of foreign substances

4.1.3 In terms of physical and chemical parameters, rectified ethyl alcohol from food raw materials must meet the requirements specified in Table 2.

table 2


Name indicator	Standard for alcohol
	first class	highest purification
Volume fraction of ethyl alcohol, %, not less
Purity test with sulfuric acid	Withstands
Oxidation test, min, at 20 °C, not less
Mass concentration of acetaldehyde in terms of anhydrous alcohol, mg/dm, no more
Mass concentration of fusel oil (1-propanol, 2-propanol, isobutyl alcohol, 1-butanol and isoamyl alcohol) in terms of anhydrous alcohol, mg/dm, no more
Mass concentration of esters (methyl acetate, ethyl acetate) in terms of anhydrous alcohol, mg/dm, no more
Volume fraction of methyl alcohol in terms of anhydrous alcohol, %, no more
Mass concentration of free acids (without ) in terms of anhydrous alcohol, mg/dm, no more
Mass concentration of dry residue in terms of anhydrous alcohol, mg/dm, no more	Not normal rushes	Not normal rushes	Not normal rushes	Not normal rushes	Not normal rushes
Mass concentration of volatile nitrogenous bases, in terms of nitrogen, in 1 dm3, anhydrous alcohol, mg, no more	Not normal rushes	Not normal rushes	Not normal rushes	Not normal rushes	Not normal rushes
Note - It is allowed to produce rectified ethyl alcohols from food raw materials of other types in accordance with regulatory documents in force in the territory of states that have adopted the standard.

4.1.4 The presence of furfural in alcohol is not allowed.

4.2 Requirements for raw materials and supplies

4.2.1 Rectified ethyl alcohols:

- “Lux” - produced from various types of grain and their mixtures in various ratios;

- “Extra” - produced from various types of grain and their mixtures in various ratios, a mixture of grain and potatoes (the amount of potato starch in the mixture should not exceed 60%);

- “Alpha” - produced from wheat, rye or a mixture of wheat and rye in various proportions;

- “Basis” - produced from any raw material of agricultural origin (with the exception of fruit).

4.2.2 Ethyl rectified alcohol of the highest purification and first grade, depending on the feedstock, is produced:

- from grain, potatoes or a mixture of grain and potatoes;

- from a mixture of grain, potatoes, sugar beets and molasses, raw sugar and other sugar- and starch-containing raw materials in various proportions;

- from molasses;

- from the head fraction of ethyl alcohol obtained during the production of alcohol from food raw materials.

The use of rectified ethyl alcohol produced from the head fraction of ethyl alcohol for the production of vodka and liqueurs is not allowed.

4.3 Packaging

4.3.1 Rectified ethyl alcohol from food raw materials is poured into specially equipped tanks or containers intended for it, made of materials approved for contact with a product of this type.

4.3.2 Tanks and reservoirs must be hermetically sealed with lids and have air vents equipped with safety valves. To establish the alcohol level, float or other safe level indicators are used.

4.3.3 Tanks and containers containing alcohol must be sealed.

4.3.4 It is allowed to bottle rectified ethyl alcohol from food raw materials into clean barrels in accordance with GOST 13950 or GOST 6247, bottles - in accordance with regulatory documents in force in the territory of the state that has adopted the standard, canisters - in accordance with GOST 5105 and other containers made from materials approved for contact with a product of this type, which must be sealed or sealed. Packaging and capping of containers with rectified ethyl alcohol must ensure its safety and comply with the requirements or regulations in force in the territory of the state that has adopted the standard, GOST 26319.

- volume, 10 dm;

- gross weight, kg;

- number of the barrel, bottle, canister, tank;

- the inscription “flammable liquid”;

- danger sign, classification code, number.

5.1 Rectified ethyl alcohol from food raw materials, in terms of the degree of impact on the human body, belongs to the 4th hazard class according to GOST 12.1.007.

The maximum permissible concentration (MPC) of ethyl alcohol vapor in the air of the working area of industrial premises is 1000 mg/m.

5.2 Rectified ethyl alcohol from food raw materials is a colorless, flammable liquid. Flash point - not less than 13 °C, auto-ignition temperature - not less than 404 °C.

Category and explosion hazard group of a mixture of ethyl alcohol with air - 11 A-T2 according to GOST 12.1.044 *.
________________
* Letter of Rosstandart dated July 23, 2018 N АШ-12186/03 clarifies that “There was a typo in clause 5.2 of GOST 5962-2013.” Should read: Category and explosion hazard group of a mixture of ethyl alcohol with air - II A-T2, determination is carried out according to GOST 12.1.044. - Database manufacturer's note.

5.3 Tanks, process equipment, pipelines and unloading devices associated with the reception, storage and movement of rectified ethyl alcohol must be protected from static electricity in accordance with the rules for protection against static electricity.

Electrical equipment must be explosion-proof.

5.4 In emergency conditions with an increased concentration of ethyl rectified alcohol in the air, as well as in case of fire, personal respiratory protection equipment and gas masks should be used.

5.5 Fire extinguishing agents: sprayed water, sand, asbestos blanket, all types of fire extinguishers.

5.6 When working with rectified ethyl alcohol, special clothing should be used in accordance with industry standards.

6.1 Acceptance rules - according to GOST 32036;
- determination of the presence of furfural - according to GOST 32013;

- determination of the mass concentration of furfural - according to GOST 32070.

8.1 Rectified ethyl alcohol from food raw materials is transported by all modes of transport in accordance with the rules for the transportation of dangerous goods in force for this type of transport and the rules for the transportation of liquid cargo in bulk in tank cars in force for railway transport.

8.2 Storage of rectified ethyl alcohol from food raw materials is carried out in accordance with the instructions for acceptance, storage, dispensing, transportation and accounting of ethyl alcohol. N 881

Electronic document text
prepared by Kodeks JSC and verified against:
official publication
M.: Standartinform, 2014

INTERSTATE COUNCIL FOR STANDARDIZATION, METROLOGY AND CERTIFICATION

INTERSTATE

STANDARD

Official publication

Rtiiform 2014 stand

Preface

The goals, basic principles and basic procedure for carrying out work on interstate standardization are established by GOST 1.0-92 “Interstate standardization system. Basic provisions" and GOST 1.2-2009 n Interstate standardization system. Interstate standards, rules and recommendations for interstate standardization. Rules for development, adoption, application, updating and cancellation"

Standard information

1 DEVELOPED by the State Scientific Institution “All-Russian” Research Institute of Food Biotechnology” of the Russian Agricultural Academy (GNU VNIIPBT Russian Agricultural Academy)

2 INTRODUCED by the Federal Agency for Technical Regulation and Metrology (Rosstandart)

3 ADOPTED by the Interstate Council for Standardization, Metrology and Certification (Minutes dated June 7, 2013 No. 43)

4 By Order of the Federal Agency for Technical Regulation and Metrology dated June 28, 2013 No. 345-st, the interstate standard GOST 5962-2013 was put into effect as a national standard of the Russian Federation on July 1, 2014.

5 8DRIVEN FOR THE FIRST TIME

Information about changes to this standard is published in the annual information index “National Standards”, and the text of the changes is in the monthly information index “National Standards”. In case of revision (replacement) or cancellation of this standard, the corresponding notice will be published in the monthly information index “National Standards”. Relevant information, notices and texts are also posted on the public information system - on the official website of the Federal Agency for Technical Regulation and Metrology on the Internet

©Standardinform, 2014

In the Russian Federation, this standard cannot be reproduced in whole or in part. replicated and distributed as an official publication without permission from the Federal Agency for Technical Regulation and Metrology

INTERSTATE STANDARD

RECTIFIED ETHYL ALCOHOL FROM FOOD RAW MATERIALS

Specifications

Rectified ethyl alcohol from edible raw matenai. Specifications

Date of introduction - 2014-07-01

1 area of use

This standard applies to rectified ethyl liquor from various types of grain, potatoes, sugar beets, raw sugar, molasses and other sugar- and starch-containing food raw materials (except for fruit) and obtained by distillation of alcohol mash or rectification of raw ethyl alcohol, as well as produced from the head fraction of ethyl alcohol obtained during the production of alcohol from food raw materials.

Product safety requirements are set out in 4.1.3 (in terms of the volume fraction of methyl alcohol), labeling requirements - in 4.4. to packaging - in 4.3.

8 of this standard uses normative references to the following interstate standards:

GOST 12.1.007-76 System of occupational safety standards. Harmful substances. Classification and general safety requirements

GOST 12.1.044-89 (ISO 4589-64) System of occupational safety standards. Fire and explosion hazard of substances and materials. Nomenclature of indicators and methods for their determination GOST 5105-82 Steel cans for fuel and oils. Technical specifications GOST 6247-79 Welded steel barrels with rolling hoops on the body. Technical specifications GOST 13950-91 Steel barrels, welded and rolled with corrugations on the body. Specifications

GOST 14192-96 Marking of cargo

GOST 15846-2002 Products sent to the Far North and equivalent areas. Packaging, labeling, transportation and storage GOST 19433-88 Dangerous goods. Classification and marking GOST 26319-84 Dangerous goods. Package

GOST 30536-2013 Vodka and ethyl alcohol from food raw materials. Gas chromatographic express method for determining the content of toxic microimpurities

GOST 31685-2012 Rectified ethyl alcohol from food raw materials. Method for determining the mass concentration of dry residue

GOST 31810-2012 Rectified ethyl alcohol from food raw materials. Determination of the mass concentration of volatile nitrogenous bases by capillary electrophoresis GOST 32013-2013 Ethyl alcohol. Method for determining the presence of furfural GOST 32036-2013 Ethyl alcohol from food raw materials. Acceptance rules and methods of analysis GOST 32070-2013 Vodka and ethyl alcohol from food raw materials. Gas chromatographic method for determining the content of volatile acids and furfural

Official publication

Note - When using this standard, it is advisable to check the validity of the reference standards in the public information system - on the official website of the Federal Agency for Technical Regulation and Metrology on the Internet or using the annual information index “National Standards”, which was published as of January 1 of the current year, and on issues of the monthly information index “National Standards” for the current year. If the reference standard is replaced (changed), then when using this standard you should be guided by the replacing (changed) standard. If the reference standard is canceled without replacement, then the provision to which a reference is made to it is applied in the part that does not affect this reference.

3 Classification

3.1 Depending on the degree of purification, rectified ethyl alcohol from food raw materials is divided into:

First grade (not used for the production of alcoholic beverages);

Higher purification:

- “Base”:

"Extra";

- “Alpha”.

4 Technical requirements

4.1 Characteristics

4.1.2 In terms of organoleptic indicators, rectified ethyl alcohol from food raw materials must meet the requirements specified in Table 1.

Table 1

4.1.3 In terms of physical and chemical parameters, rectified ethyl alcohol from food raw materials must meet the requirements specified in Table 2.

table 2

End of table 2

	Alcohol norm
Indicator name			"Extra"
Mass concentration of fusel oil (1-propanol. 2-prola-nol. isobutyl alcohol. 1-butanol and ieoamyl alcohol) in terms of anhydrous alcohol. mg/dm3. no more
Mass concentration of esters (methyl acetate, ethyl acetate) in terms of anhydrous alcohol, mg/dm 3. no more
Volume fraction of methyl alcohol in terms of anhydrous alcohol. %. no more
Mass concentration of free acids (without CO 2) in terms of anhydrous alcohol, mg/dm 3. no more
Mass concentration of dry residue in terms of anhydrous alcohol, mg/dm3. no more	Not standardized	Not standardized	Not standardized	Not standardized	Not standardized
Mass concentration of volatile nitrogenous bases, in terms of nitrogen, in 1 dm 3, anhydrous alcohol, mg. no more	Not standardized	Not standardized	Not standardized	Not standardized	Not standardized
Note - It is allowed to produce rectified ethyl alcohols from food raw materials of other types in accordance with regulatory documents in force in the territory of states that have adopted the standard.

4.1.4 The presence of furfural in alcohol is not allowed.

4.2 Requirements for raw materials and supplies

4.2.1 Rectified ethyl alcohols:

“Lux” - produced from various types of grain and their mixtures in various ratios:

“Extra” - produced from various types of grain and their mixtures in various ratios, a mixture of grain and potatoes (the amount of potato starch in the mixture should not exceed 60%):

“Alpha” - produced from wheat, rye or a mixture of wheat and rye in various ratios:

- “Basis” - produced from any raw material of agricultural origin (with the exception of fruit).

4.2.2 Ethyl rectified alcohol of the highest purification and first grade, depending on the feedstock, is produced:

From grain, potatoes or a mixture of grain and potatoes;

From a mixture of grain, potatoes, sugar beets and molasses, raw sugar and other sugar- and starch-containing raw materials in various proportions;

From molasses:

From the head fraction of ethyl alcohol obtained during the production of alcohol from food raw materials.

The use of rectified ethyl alcohol produced from the head fraction of ethyl alcohol for the production of vodka and liqueurs is not allowed.

4.3 Packaging

4.3.1 Rectified ethyl alcohol from food raw materials is poured into specially equipped tanks or containers intended for it, made of materials approved for contact with a product of this type.

4.3.2 Tanks and reservoirs must be hermetically sealed with lids and have air vents equipped with safety valves. To establish the alcohol level, float or other safe level indicators are used.

4.3.3 Tanks and containers containing alcohol must be sealed.

4.3.4 It is allowed to bottle rectified ethyl alcohol from food raw materials into clean barrels in accordance with GOST 13950 or GOST 6247. bottles - in accordance with regulatory documents in force in the territory of the state that has adopted the standard, canisters in accordance with GOST 5105 and other containers made from materials. permitted for contact with a product of this type, which must be sealed or sealed. Packaging and capping of containers with rectified ethyl alcohol must ensure its safety and comply with the requirements (2] or regulatory legal acts in force in the territory of the state that has adopted the standard. GOST 26319.

4.3.5 Packaging of rectified ethyl alcohol for deliveries to the Far North and equivalent areas should be carried out in accordance with the requirements of GOST 15846.

4.4 Marking

4.4.1 Transport marking - according to the regulations and legal acts in force in the territory of the state that has adopted the standard. GOST 14192. Marking characterizing the transport danger of cargo - according to GOST 19433 with additional information:

Volume. 10 dm 3;

Gross weight, kg.

Number of the barrel, bottle, canister, tank;

The inscription “flammable liquid”;

Danger sign, classification code, number.

5 Safety requirements

5.1 Rectified ethyl alcohol from food raw materials, in terms of the degree of impact on the human body, belongs to the 4th hazard class according to GOST 12.1.007.

The maximum permissible concentration (MPC) of ethyl alcohol vapors in the air of the working area of industrial premises is 1000 mg/m3.

5.2 Rectified ethyl alcohol from food raw materials is a colorless, flammable liquid. Flash point - not less than 13 °C. auto-ignition temperature - not less than 404 °C.

Electrical equipment must be explosion-proof.

5.4 In emergency conditions with an increased concentration of ethyl rectified alcohol in the air, as well as in case of fire, personal respiratory protection equipment and gas masks should be used.

5.5 Fire extinguishing agents: sprayed water, sand, asbestos blanket, all types of fire extinguishers.

5.6 When working with rectified ethyl alcohol, special clothing should be used in accordance with industry standards.

6 Acceptance rules

6.1 Acceptance rules - according to GOST 32036.

7 Methods of analysis

7.1 Sampling - according to GOST 32036.

7.2 Methods of analysis:

Determination of the volume fraction of ethyl alcohol - according to GOST 32036;

Test for purity with sulfuric acid - GOST 32036;

Test for oxidation - according to GOST 32036:

About prel outside and in the mass concentration of acetaldehyde, fusel oil, esters, volume fraction of methyl alcohol - according to GOST 30536:

Determination of mass concentration of free acids - according to GOST 32036:

Determination of mass concentration of dry residue - according to GOST 31665:

Determination of mass concentration of volatile nitrogenous bases - according to GOST 31810:

Determination of the presence of furfural - according to GOST 32013:

Determination of the mass concentration of furfural - according to GOST 32070.

8 Transportation and storage

8.2 Storage of rectified ethyl alcohol from food raw materials is carried out in accordance with the instructions for acceptance, storage, dispensing, transportation and accounting of ethyl alcohol.

8.3 The shelf life of ethyl alcohol is unlimited.

bibliography

11) TR TS 021/2011

12) TR TS 005/2011 (3) TR TS 022/2011

Technical Regulations of the Customs Union “On Food Safety” No. 860

Technical Regulations of the Customs Union “On Packaging Safety” No. 769 Technical Regulations of the Customs Union “Food Products and Parts of Its Labeling” No. 881

UDC 663.5:006.354 MKS 67.160.10 N74

Key words: rectified ethyl alcohol, classification, technical requirements, dangerous goods, packaging, labeling, flammable liquid

Editor L.v. Kore t ni koal Technical editor V.N. Prus school Proofreader M.I. Pershina Computer paper by A. N. Zolotareva

Completed set Yu.12.201E. Signed and started 01/13/2014. Format VO "84^ Typeface Arial. Uel. p. 0.93. Academic-kzd. p. 0.65. Circulation 123 eo. Eak. 23

Published and printed by EO FSUE “STANDARTINFORMx. 123995 Mosdaa. Grenade Lane.. 4.

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INTERSTATE COUNCIL FOR STANDARDIZATION, METROLOGY AND CERTIFICATION

INTERSTATE

STANDARD

Official publication

Standardinform

Standard information

1 DEVELOPED by the State Scientific Institution “All-Russian” Research Institute of Food Biotechnology” of the Russian Agricultural Academy (GNU VNIIPBT Russian Agricultural Academy)

2 INTRODUCED by the Federal Agency for Technical Regulation and Metrology (Rosstandart)

3 ADOPTED by the Interstate Council for Standardization, Metrology and Certification (protocol dated June 7, 2013 No. 43)

5 INTRODUCED FOR THE FIRST TIME

Information about changes to this standard is published in the annual information index “National Standards”, and the text of changes and amendments is published in the monthly information index “National Standards”. In case of revision (replacement) or cancellation of this standard, the corresponding notice will be published in the monthly information index “National Standards”. Relevant information, notifications and texts are also posted in the public information system - on the official website of the Federal Agency for Technical Regulation and Metrology on the Internet

©Standardinform, 2014

In the Russian Federation, this standard cannot be fully or partially reproduced, replicated and distributed as an official publication without permission from the Federal Agency for Technical Regulation and Metrology

4.3.5 Packaging of ethyl rectified alcohol for deliveries to the Far North and equivalent areas should be carried out in accordance with the requirements of GOST 15846.

4.4.1 Transport marking - according to or regulatory legal acts in force in the territory of the state that has adopted the standard, GOST 14192. Marking characterizing the transport danger of the cargo - in accordance with GOST 19433 with additional information:

Volume, 10 dm 1;

Gross weight, kg;

Number of the barrel, bottle, canister, tank;

The inscription “flammable liquid”;

Signs, classification code, number.

5.1 Rectified ethyl alcohol from food raw materials, in terms of the degree of impact on the human body, belongs to the 4th hazard class according to GOST 12.1.007.

The maximum permissible concentration (MPC) of ethyl alcohol vapor in the air of the working area of industrial premises is 1000 mg/m 1 .

5.2 Rectified ethyl alcohol from food raw materials is a colorless, flammable liquid. Flash point - not less than 13 °C, auto-ignition temperature - not less than 404 °C.

Electrical equipment must be explosion-proof.

5.4 In emergency conditions with an increased concentration of ethyl rectified alcohol in the air, as well as in case of fire, personal respiratory protection equipment and gas masks should be used.

5.5 Fire extinguishing agents: sprayed water, sand, asbestos blanket, all types of fire extinguishers.

5.6 When working with rectified ethyl alcohol, special clothing should be used in accordance with industry standards.

;

Determination of the presence of furfural - according to GOST 32013;

Determination of mass concentration of furfural - according to GOST 32070.

8.2 Storage of rectified ethyl alcohol from food raw materials is carried out in accordance with the instructions for acceptance, storage, dispensing, transportation and accounting of ethyl alcohol.

8.3 The shelf life of ethyl alcohol is unlimited.

Regulations of the Customs Union “On Food Safety”

regulation of the Customs Union “On the safety of packaging” No. 769 regulation of the Customs Union “Food products in terms of their labeling” 3

UDC 663.5:006.354 MKS 67.160.10 N74

Key words: rectified ethyl alcohol, classification, technical requirements, dangerous goods, packaging, labeling, flammable liquid

Editor L.V. Koretnikova Technical editor V.N. Prusakova Corrector M.I. Pershina Computer layout A.N. Zolotareva

Delivered for recruitment on 12/10/2013. Signed for publication on January 13, 2014. Format 60x84Uy. Typeface Ariap.

Uel. oven l. 0.93. Academic ed. l. 0.65. Circulation 123 copies. Zach. 23.

Published and printed by FSUE STANDARDINFORM, 123995 Moscow, Granatny per., 4. www.gostinfo.ru [email protected]

INTERSTATE COUNCIL FOR STANDARDIZATION, METROLOGY AND CERTIFICATION

INTERSTATE

STANDARD GOST

RECTIFIED ETHYL ALCOHOL FROM FOOD RAW MATERIALS

Technical specifications

Official publication

Moscow S thai dar tnnfor m 2013

End of table 2

Name			Standard for alcohol
indicator
Mass concentration of dry residue in terms of
for anhydrous alcohol,
mg/dm 3, no more
Mass concentration of volatile nitrogenous bases, in terms of nitrogen, in 1 dm 3, without
aqueous alcohol, mg,

Note - It is allowed to produce rectified ethyl alcohols from food raw materials of other types in accordance with regulatory documents in force in the territory of states that have adopted the standard.

4.1.4 The presence of furfural in alcohol is not allowed.

4.2 Requirements for raw materials and supplies

4.2.1 Rectified ethyl alcohols:

- “Lux” - produced from various types of grain and their mixtures in various ratios,

- “Extra” - produced from various types of grain and their mixtures in various ratios, a mixture of grain and potatoes (the amount of potato starch in the mixture should not exceed 60%);

- “Alpha” - produced from wheat, rye or a mixture of wheat and rye in various proportions,

- “Basis” - produced from any raw material of agricultural origin (with the exception of fruit).

4.2.2 Ethyl rectified alcohol of the highest purification and first grade is produced depending on the source raw material

From grain, spruce potatoes or from a mixture of grain and spruce potatoes,

From a mixture of grain, potatoes, sugar beets and molasses, raw sugar and other sugar- and starch-containing raw materials in various proportions,

From molasses;

From the head fraction of ethyl alcohol obtained during the production of alcohol from food raw materials

The use of rectified ethyl alcohol produced from the head fraction of ethyl alcohol for the production of vodka and liqueurs is not allowed.

4.3 Packaging

4.3.1 Rectified ethyl alcohol from food raw materials is poured into specially equipped tanks or containers intended for it, made of materials approved for contact with a product of this type.

4.3.2 Tanks and reservoirs must be hermetically sealed with lids and have air vents equipped with safety valves. To establish the alcohol level, float or other non-hazardous level indicators are used.

4.3.3 Tanks and containers containing alcohol must be sealed.

types that must be sealed or sealed. Packaging and capping of containers with rectified ethyl alcohol must ensure its safety and comply with the requirements or regulations in force in the territory of the state that has adopted the standard, GOST 26319.

4.3.5 Packaging of ethyl rectified alcohol for deliveries to the Far North and equivalent areas must be carried out in accordance with the requirements of GOST 15846.

4.4 Marking

4.4.1 Transport marking - according to or regulatory legal acts in force in the territory of the state that has adopted the standard, GOST 14192. Marking characterizing the transport danger of the cargo - according to GOST 19433, indicating additional information:

Volume, 10 dm 3;

Gross weight, kg;

Number of the barrel, bottle, canister, tank;

The inscription “flammable liquid”;

Danger sign, classification code, number.

5 Safety requirements

5.1 Rectified ethyl alcohol from food raw materials, in terms of the degree of impact on the human body, belongs to the 4th hazard class according to GOST 12.1.007.

The maximum permissible concentration (MPC) of ethyl alcohol vapor in the air of the working area of industrial premises is 1000 mg/m 3 .

5.2 Rectified ethyl alcohol from food raw materials is a colorless, flammable liquid. Flash point - not less than 13 °C, auto-ignition temperature - not less than 404 °C.

Electrical equipment must be explosion-proof.

5.4 In emergency conditions with an increased concentration of ethyl rectified alcohol in the air, as well as in case of fire, personal respiratory protection equipment and gas masks should be used.

5.5 Fire extinguishing agents: sprayed water, sand, asbestos blanket, all types of fire extinguishers.

5.6 When working with rectified ethyl alcohol, special clothing should be used in accordance with industry standards.

6 Acceptance rules

6.1 Acceptance rules - according to GOST 32036.

7 Methods of analysis

7.1 Sampling - according to GOST 32036.

7.2 Methods of analysis:

Determination of the volume fraction of ethyl alcohol - according to GOST 32036;

Purity test with sulfuric acid - GOST 32036;

Test for oxidation - according to GOST 32036;

Determination of the mass concentration of acetaldehyde, fusel oil, esters, volume fraction of methyl alcohol - according to GOST 30536;

Determination of mass concentration of free acids - according to GOST 32036;

Determination of mass concentration of dry residue - according to GOST 31685;

Determination of mass concentration of volatile nitrogenous bases - according to GOST 31810;

Determination of the presence of furfural - according to GOST 32013;

Determination of the mass concentration of furfural - according to GOST 32070.

8 Transportation and storage

8.2 Storage of rectified ethyl alcohol from food raw materials is carried out in accordance with the instructions for acceptance, storage, dispensing, transportation and accounting of ethyl alcohol.

8.3 The shelf life of ethyl alcohol is unlimited.

Bibliography Afiya

TR CU 021/2011 Technical regulations of the Customs Union “On safety

of food products" No. 880

TR CU 005/2011 Technical regulations of the Customs Union “On safety

Packaging No. 769

TR CU 022/2011 Technical regulations of the Customs Union “Food

products regarding their labeling" No. 881

UDC 663.5:006.354 MESS 67.160.10 N74

Keywords rectified ethyl alcohol, classification, technical requirements, dangerous goods, packaging, labeling, flammable liquid

Interstate standard GOST 5962-2013

"RECTIFIED ETHYL ALCOHOL FROM FOOD RAW MATERIALS. TECHNICAL CONDITIONS"

(approved by order of the Federal Agency for Technical Regulation and Metrology dated June 28, 2013 N 345-st)

Rectified ethyl alcohol from edible raw material. Specifications

Introduced for the first time

Product safety requirements are set out in 4.1.3 (in terms of the volume fraction of methyl alcohol), labeling requirements - in 4.4, and packaging requirements - in 4.3.

This standard uses normative references to the following interstate standards:

GOST 12.1.007-76 System of occupational safety standards. Harmful substances. Classification and general safety requirements

GOST 12.1.044-89 (ISO 4589-84) System of occupational safety standards. Fire and explosion hazard of substances and materials. Nomenclature of indicators and methods for their determination

GOST 5105-82 Steel cans for fuel and oils. Specifications

GOST 6247-79 Welded steel barrels with rolling hoops on the body. Specifications

GOST 13950-91 Welded and rolled steel barrels with corrugations on the body. Specifications

GOST 14192-96 Marking of cargo

GOST 15846-2002 Products sent to the Far North and equivalent areas. Packaging, labeling, transportation and storage

GOST 19433-88 Dangerous goods. Classification and labeling

GOST 26319-84 Dangerous goods. Package

GOST 30536-2013 Vodka and ethyl alcohol from food raw materials. Gas chromatographic express method for determining the content of toxic microimpurities

GOST 31685-2012 Rectified ethyl alcohol from food raw materials. Method for determining the mass concentration of dry residue

GOST 31810-2012 Rectified ethyl alcohol from food raw materials. Determination of the mass concentration of volatile nitrogenous bases by capillary electrophoresis

GOST 32013-2013 Ethyl alcohol. Method for determining the presence of furfural

GOST 32036-2013 Ethyl alcohol from food raw materials. Acceptance rules and analysis methods

GOST 32070-2013 Vodka and ethyl alcohol from food raw materials. Gas chromatographic method for determining the content of volatile acids and furfural

Note - When using this standard, it is advisable to check the validity of the reference standards in the public information system - on the official website of the Federal Agency for Technical Regulation and Metrology on the Internet or using the annual information index "National Standards", which was published as of January 1 of the current year, and on issues of the monthly information index "National Standards" for the current year. If the reference standard is replaced (changed), then when using this standard you should be guided by the replacing (changed) standard. If the reference standard is canceled without replacement, then the provision in which a reference is made to it is applied in the part that does not affect this reference.

3.1 Depending on the degree of purification, rectified ethyl alcohol from food raw materials is divided into:

First grade (not used for the production of alcoholic beverages);

Highest purity;

- "Extra";

4.1 Characteristics

4.1.2 In terms of organoleptic indicators, rectified ethyl alcohol from food raw materials must meet the requirements specified in Table 1.

Table 1

4.1.3 In terms of physical and chemical parameters, rectified ethyl alcohol from food raw materials must meet the requirements specified in Table 2.

table 2

Indicator name	Standard for alcohol
Indicator name	first class	highest purification
Volume fraction of ethyl alcohol,%, not less
Purity test with sulfuric acid	Withstands
Oxidation test, min, at 20°C, not less
Mass concentration of acetaldehyde in terms of anhydrous alcohol, mg/dm 3, no more
Mass concentration of fusel oil (1-propanol, 2-propanol, isobutyl alcohol, 1-butanol and isoamyl alcohol) in terms of anhydrous alcohol, mg/dm 3, no more
Mass concentration of esters (methyl acetate, ethyl acetate) in terms of anhydrous alcohol, mg/dm 3, no more
Volume fraction of methyl alcohol in terms of anhydrous alcohol, %, no more
Mass concentration of free acids (without CO 2) in terms of anhydrous alcohol, mg/dm 3, no more
Mass concentration of dry residue in terms of anhydrous alcohol, mg/dm 3, no more	Not standardized	Not standardized	Not standardized	Not standardized	Not standardized
Mass concentration of volatile nitrogenous bases, in terms of nitrogen, in 1 dm 3, anhydrous alcohol, mg, no more	Not standardized	Not standardized	Not standardized	Not standardized	Not standardized
Note - It is allowed to produce rectified ethyl alcohols from food raw materials of other types in accordance with regulatory documents in force in the territory of states that have adopted the standard

4.1.4 The presence of furfural in alcohol is not allowed.

4.2 Requirements for raw materials and supplies

4.2.1 Rectified ethyl alcohols:

- “Lux” - produced from various types of grain and their mixtures in various ratios;

- “Extra” - produced from various types of grain and their mixtures in various ratios, a mixture of grain and potatoes (the amount of potato starch in the mixture should not exceed 60%);

- “Alpha” - produced from wheat, rye or a mixture of wheat and rye in various proportions;

- “Basis” - produced from any raw material of agricultural origin (with the exception of fruit).

4.2.2 Ethyl rectified alcohol of the highest purification and first grade, depending on the feedstock, is produced:

From grain, potatoes or a mixture of grain and potatoes;

From a mixture of grain, potatoes, sugar beets and molasses, raw sugar and other sugar- and starch-containing raw materials in various proportions;

From molasses;

From the head fraction of ethyl alcohol obtained during the production of alcohol from food raw materials.

The use of rectified ethyl alcohol produced from the head fraction of ethyl alcohol for the production of vodka and liqueurs is not allowed.

4.3 Packaging

4.3.1 Rectified ethyl alcohol from food raw materials is poured into specially equipped tanks or containers intended for it, made of materials approved for contact with a product of this type.

4.3.2 Tanks and reservoirs must be hermetically sealed with lids and have air vents equipped with safety valves. To establish the alcohol level, float or other safe level indicators are used.

4.3.3 Tanks and containers containing alcohol must be sealed.

4.3.4 It is allowed to pour ethyl rectified alcohol from food raw materials into clean barrels in accordance with GOST 13950 or GOST 6247, bottles - in accordance with regulatory documents in force in the territory of the state that has adopted the standard, canisters in accordance with GOST 5105 and other containers made from materials permitted for contact with a product of this type, which must be sealed or sealed. Packaging and capping of containers with rectified ethyl alcohol must ensure its safety and comply with the requirements or regulations in force in the territory of the state that has adopted the standard, GOST 26319.

4.3.5 Packaging of rectified ethyl alcohol for deliveries to the Far North and equivalent areas should be carried out in accordance with the requirements of GOST 15846.

4.4 Marking

4.4.1 Transport marking - according to or regulatory legal acts in force in the territory of the state that has adopted the standard, GOST 14192. Marking characterizing the transport danger of the cargo - according to GOST 19433, indicating additional information:

Volume, 10 dm 3;

Gross weight, kg;

Number of the barrel, bottle, canister, tank;

The inscription "flammable liquid";

Danger sign, classification code, number.

5.1 Rectified ethyl alcohol from food raw materials, in terms of the degree of impact on the human body, belongs to the 4th hazard class according to GOST 12.1.007.

The maximum permissible concentration (MPC) of ethyl alcohol vapor in the air of the working area of industrial premises is 1000 mg/m 3 .

5.2 Rectified ethyl alcohol from food raw materials is a colorless, flammable liquid. Flash point - not less than 13°C, auto-ignition temperature - not less than 404°C.

Electrical equipment must be explosion-proof.

5.4 In emergency conditions with an increased concentration of ethyl rectified alcohol in the air, as well as in case of fire, personal respiratory protection equipment and gas masks should be used.

5.5 Fire extinguishing agents: sprayed water, sand, asbestos blanket, all types of fire extinguishers.

5.6 When working with rectified ethyl alcohol, special clothing should be used in accordance with industry standards.

6.1 Acceptance rules - according to GOST 32036.

7.1 Sampling - according to GOST 32036.

7.2 Methods of analysis:

Determination of the volume fraction of ethyl alcohol - according to GOST 32036;

Purity test with sulfuric acid - GOST 32036;

Test for oxidation - according to GOST 32036;

Determination of the mass concentration of acetaldehyde, fusel oil, esters, volume fraction of methyl alcohol - according to GOST 30536;

Determination of mass concentration of free acids - according to GOST 32036;

Determination of mass concentration of dry residue - according to GOST 31685;

Determination of mass concentration of volatile nitrogenous bases - according to GOST 31810;

Determination of the presence of furfural - according to GOST 32013;

Determination of the mass concentration of furfural - according to GOST 32070.

Standard for alcohol

Volume fraction of ethyl alcohol. %. no less

Purity test with sulfuric acid

Withstands

Oxidation test. min. at 20 °C. no less

Mass concentration of acetaldehyde in terms of anhydrous alcohol, mg/dm*. no more

8.2 Storage of rectified ethyl alcohol from food raw materials is carried out in accordance with the instructions for acceptance, storage, dispensing, transportation and accounting of ethyl alcohol.

8.3 The shelf life of ethyl alcohol is unlimited.

Bibliography